Literature DB >> 12950188

A fluorescent E-poly(p-phenylenephosphaalkene) prepared by a phospha-Wittig reaction.

Rhett C Smith1, Xufang Chen, John D Protasiewicz.   

Abstract

A soluble (E)-poly(p-phenylenephosphaalkene) having sterically encumbering ligands has been prepared by a phospha-Wittig reaction. This material exhibits a bathochromic shift with respect to E-PPV and with respect to representative model oligomers. We also report the first fluorescence study of a poly(p-phenylenephosphaalkene) and find that this material exhibits fluorescence, though with modest intensity relative to similarly sized carbon-based analogues.

Entities:  

Year:  2003        PMID: 12950188     DOI: 10.1021/ic0345471

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  3 in total

1.  Chromo- and fluorophoric water-soluble polymers and silica particles by nucleophilic substitution reaction of poly(vinyl amine).

Authors:  Katja Hofmann; Ingolf Kahle; Frank Simon; Stefan Spange
Journal:  Beilstein J Org Chem       Date:  2010-07-22       Impact factor: 2.883

2.  Phosphaalkenylidene bridged ferrocenes.

Authors:  Andreas Orthaber; Rolfe H Herber; Rudolf Pietschnig
Journal:  J Organomet Chem       Date:  2012-11-15       Impact factor: 2.369

3.  Alternative Synthesis and Structures of C-monoacetylenic Phosphaalkenes.

Authors:  Andreas Orthaber; Elisabet Öberg; Reuben T Jane; Sascha Ott
Journal:  Z Anorg Allg Chem       Date:  2012-10-09       Impact factor: 1.492

  3 in total

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