| Literature DB >> 12945902 |
Iain Coldham1, Kathy N Price, Richard E Rathmell.
Abstract
Tin-lithium exchange allows the formation of alpha-amino-organolithium species that undergo anionic cyclization onto allylic ethers to give 3-alkenylpyrrolidines. The methodology has been applied to the synthesis of an advanced intermediate related to the natural product (-)-alpha-kainic acid.Entities:
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Year: 2003 PMID： 12945902 DOI： 10.1039/b303670g
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876