Literature DB >> 12945692

Palladium-tetraphosphine complex: an efficient catalyst for the coupling of aryl halides with alkynes.

Marie Feuerstein1, Florian Berthiol, Henri Doucet, Maurice Santelli.   

Abstract

The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)-cyclopentane-[PdCl(eta3-C3H5)]2 system catalyses the coupling of aryl halides with alkynes with very high ratios of substrates-catalyst in good yields; a turnover number of 2600000 can be obtained for the reaction of 4-trifluoromethylbromobenzene with phenylacetylene in the presence of this catalyst.

Entities:  

Year:  2003        PMID: 12945692     DOI: 10.1039/b306428j

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

1.  3-[4-(Trifluoro-meth-yl)phen-yl]propanoic acid.

Authors:  Jian-Ning Guan; Xiang-Jun Kong; Bin Xu; Jin-Hua Liang; Na Song
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-03-25

2.  Sonogashira reaction of aryl and heteroaryl halides with terminal alkynes catalyzed by a highly efficient and recyclable nanosized MCM-41 anchored palladium bipyridyl complex.

Authors:  Bo-Nan Lin; Shao-Hsien Huang; Wei-Yi Wu; Chung-Yuan Mou; Fu-Yu Tsai
Journal:  Molecules       Date:  2010-12-10       Impact factor: 4.411

  2 in total

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