Literature DB >> 12944641

The infinite double-stranded chain polymer catena-poly[[bis(dicyanamido)zinc(II)]-di-mu-1,2-bis(1,2,4-triazol-1-yl)ethane-kappa4N4:N4'].

Baolong Li1, Baozong Li, Xia Zhu, Liming Zhu, Yong Zhang.   

Abstract

The coordination geometry of the Zn(II) atom in the title complex, [Zn(C(2)N(3))(2)(C(6)H(8)N(6))(2)](n) or [Zn(dca)(2)(bte)(2)](n), where bte is mu-1,2-bis(1,2,4-triazol-1-yl)ethane and dca is dicyanamide, is distorted compressed octahedral, in which the Zn(II) atom lies on an inversion center and coordinates four N atoms from the triazole rings of four symmetry-related bte ligands and two N atoms from two symmetry-related monodentate dca ligands. The structure is polymeric, with 18-membered spiro-fused rings extending in the b direction and each 18-membered ring involving two inversion-related bte molecules.

Entities:  

Year:  2003        PMID: 12944641     DOI: 10.1107/s0108270103012435

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Bis[μ-1,2-bis-(1,2,4-triazol-4-yl)ethane]bis-[diiodidozinc(II)].

Authors:  Yunfei Feng; Na Liang; Baolong Li; Haiyan Li
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-04-24
  1 in total

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