Literature DB >> 12940734

A convenient method for the preparation of inverted tert-alkyl carboxylates from chiral tert-alcohols by a new type of oxidation-reduction condensation using 2,6-dimethyl-1,4-benzoquinone.

Teruaki Mukaiyama1, Taichi Shintou, Kentaro Fukumoto.   

Abstract

Oxidation-reduction condensation using in situ-formed alkoxydiphenylphosphines, 2,6-dimethyl-1,4-benzoquinone, and carboxylic acids provided a new and efficient method for the preparation of inverted tert-alkyl carboxylates from various chiral tertiary alcohols.

Entities:  

Year:  2003        PMID： 12940734     DOI： 10.1021/ja0303844

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  Stereoinversion of Unactivated Alcohols by Tethered Sulfonamides.

Authors:  Paul T Marcyk; Latisha R Jefferies; Deyaa I AbuSalim; Maren Pink; Mu-Hyun Baik; Silas P Cook
Journal:  Angew Chem Int Ed Engl       Date:  2019-01-15       Impact factor: 15.336

2.  New insights into the structure and reduction of graphite oxide.

Authors:  Wei Gao; Lawrence B Alemany; Lijie Ci; Pulickel M Ajayan
Journal:  Nat Chem       Date:  2009-07-05       Impact factor: 24.427

3.  Male-produced aggregation pheromone of the lesser mealworm beetle, Alphitobius diaperinus.

Authors:  Robert J Bartelt; Bruce W Zilkowski; Allard A Cossé; C Dayton Steelman; Narinderpal Singh
Journal:  J Chem Ecol       Date:  2009-04-01       Impact factor: 2.626

4.  Enantioselective synthesis of tertiary α-chloro esters by non-covalent catalysis.

Authors:  Richard Y Liu; Masayuki Wasa; Eric N Jacobsen
Journal:  Tetrahedron Lett       Date:  2015-06-03       Impact factor: 2.415

5.  Nine new farnesylphenols from the basidiomycete albatrellus caeruleoporus.

Authors:  Liang-Yan Liu; Zheng-Hui Li; Gang-Qiang Wang; Kun Wei; Ze-Jun Dong; Tao Feng; Gen-Tao Li; Yan Li; Ji-Kai Liu
Journal:  Nat Prod Bioprospect       Date:  2014-04-23

6.  Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers.

Authors:  Xu Chen; Ilan Marek
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-11       Impact factor: 16.823

Review 7.  Stereospecific nucleophilic substitution at tertiary and quaternary stereocentres.

Authors:  Veeranjaneyulu Lanke; Ilan Marek
Journal:  Chem Sci       Date:  2020-07-28       Impact factor: 9.825
  7 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.