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Literature DB >> 12940721

One-electron oxidized nickel(II)-(disalicylidene)diamine complex: temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states.

Yuichi Shimazaki¹, Fumito Tani, Kôichi Fukui, Yoshinori Naruta, Osamu Yamauchi.

Abstract

The one-electron oxidized species of a Ni(II)-phenolate complex has been shown to be in the Ni(II)-phenoxyl radical state at room temperature and the Ni(III)-phenolate state at < -120 degrees C, indicating that the oxidation state is temperature dependent.

Entities: Chemical

Year: 2003 PMID： 12940721 DOI： 10.1021/ja035806o

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

7 in total

1. Ligand radical localization in a nonsymmetric one-electron oxidized Ni(II) bis-phenoxide complex.

Authors: Tim Storr; Pratik Verma; Yuichi Shimazaki; Erik C Wasinger; T Daniel P Stack
Journal: Chemistry Date: 2010-08-09 Impact factor: 5.236

2. Towards a tunable molecular memory that fits into a (10 A)3 cube.

Authors: Adam Sokołowski; Wojciech Grochala
Journal: J Mol Model Date: 2005-05-12 Impact factor: 1.810

3. Detailed evaluation of the geometric and electronic structures of one-electron oxidized group 10 (Ni, Pd, and Pt) metal(II)-(disalicylidene)diamine complexes.

Authors: Yuichi Shimazaki; T Daniel P Stack; Tim Storr
Journal: Inorg Chem Date: 2009-09-07 Impact factor: 5.165

4. Syntheses, electronic structures, and EPR/UV-vis-NIR spectroelectrochemistry of nickel(II), copper(II), and zinc(II) complexes with a tetradentate ligand based on S-methylisothiosemicarbazide.

Authors: Vladimir B Arion; Peter Rapta; Joshua Telser; Sergiu S Shova; Martin Breza; Karol Luspai; Jozef Kozisek
Journal: Inorg Chem Date: 2011-03-01 Impact factor: 5.165

One-electron oxidized nickel(II)-(disalicylidene)diamine complex: temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states.

1. Ligand radical localization in a nonsymmetric one-electron oxidized Ni(II) bis-phenoxide complex.

2. Towards a tunable molecular memory that fits into a (10 A)3 cube.

3. Detailed evaluation of the geometric and electronic structures of one-electron oxidized group 10 (Ni, Pd, and Pt) metal(II)-(disalicylidene)diamine complexes.

4. Syntheses, electronic structures, and EPR/UV-vis-NIR spectroelectrochemistry of nickel(II), copper(II), and zinc(II) complexes with a tetradentate ligand based on S-methylisothiosemicarbazide.

5. Defining the electronic and geometric structure of one-electron oxidized copper-bis-phenoxide complexes.

6. Recent advances in phenoxyl radical complexes of salen-type ligands as mixed-valent galactose oxidase models.

Review 7. π-π Stacking Interaction of Metal Phenoxyl Radical Complexes.