Literature DB >> 12934891

Pinwheel motifs: formation of unusual homo- and hetero-nuclear aggregates via bridging thiolates.

Angelo J Amoroso1, Simon S M Chung, Douglas J E Spencer, Jonathan P Danks, Mark W Glenny, Alexander J Blake, Paul A Cooke, Claire Wilson, Martin Schröder.   

Abstract

The homohexanuclear complexes [Ni2[Ni(L1)]4](BF4)4 x MeCN, 1, [Pd2(Pd(L2)]4](BF4)4, 2, and the heteropentanuclear aggregate [Cu2[Ni(L3)]3](PF6)2, 3, all adopt a 'pinwheel' type structural motif via thiolate bridging between square-planar Ni(II) or Pd(II) and between trigonal planar Cu(I) centres, respectively.

Entities:  

Year:  2003        PMID: 12934891     DOI: 10.1039/b303851c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Proton affinity studies of nickel N2S2 complexes and control of aggregation.

Authors:  Nicholas A Arnet; Nattamai Bhuvanesh; Marcetta Y Darensbourg
Journal:  J Biol Inorg Chem       Date:  2019-06-07       Impact factor: 3.358

  1 in total

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