Literature DB >> 12932465

Regularized resolvent transform for direct calculation of 45 degrees projections of 2D J spectra.

Geoffrey S Armstrong1, Jianhan Chen, Kristin E Cano, A J Shaka, Vladimir A Mandelshtam.   

Abstract

The regularized resolvent transform (RRT) has been applied in a novel way to J-resolved spectra. This involves the direct calculation of the 45 degrees projection without constructing the 2D spectrum. The results show a significant resolution enhancement over that obtained by the 45 degrees projection of a 2D Fourier spectrum, even for much larger signals. In particular, RRT is able to resolve peaks that belong to different overlapping multiplets in a very crowded spectral region, where the conventional technique fails for any signal size. The resolving power of this method along with the significantly shorter signals required, make this method a powerful tool in spectral assignment.

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Year:  2003        PMID: 12932465     DOI: 10.1016/s1090-7807(03)00129-0

Source DB:  PubMed          Journal:  J Magn Reson        ISSN: 1090-7807            Impact factor:   2.229


  1 in total

1.  The GNAT: A new tool for processing NMR data.

Authors:  Laura Castañar; Guilherme Dal Poggetto; Adam A Colbourne; Gareth A Morris; Mathias Nilsson
Journal:  Magn Reson Chem       Date:  2018-03-25       Impact factor: 2.447

  1 in total

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