| Literature DB >> 12932465 |
Geoffrey S Armstrong1, Jianhan Chen, Kristin E Cano, A J Shaka, Vladimir A Mandelshtam.
Abstract
The regularized resolvent transform (RRT) has been applied in a novel way to J-resolved spectra. This involves the direct calculation of the 45 degrees projection without constructing the 2D spectrum. The results show a significant resolution enhancement over that obtained by the 45 degrees projection of a 2D Fourier spectrum, even for much larger signals. In particular, RRT is able to resolve peaks that belong to different overlapping multiplets in a very crowded spectral region, where the conventional technique fails for any signal size. The resolving power of this method along with the significantly shorter signals required, make this method a powerful tool in spectral assignment.Mesh:
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Year: 2003 PMID: 12932465 DOI: 10.1016/s1090-7807(03)00129-0
Source DB: PubMed Journal: J Magn Reson ISSN: 1090-7807 Impact factor: 2.229