Literature DB >> 12932037

A zeolite-enzyme combination for biphasic dynamic kinetic resolution of benzylic alcohols.

Stijn Wuyts1, Karolien De Temmerman, Dirk De Vos, Pierre Jacobs.   

Abstract

Acid zeolites like H-Beta are efficient heterogeneous catalysts for racemization of benzylic alcohols in water; by combination of the racemization with an enzymatic kinetic resolution in a two-phase system, enantiomerically pure esters were obtained in high yield via a dynamic kinetic resolution.

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Year:  2003        PMID: 12932037     DOI: 10.1039/b305120j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Chemoenzymatic dynamic kinetic resolution: a powerful tool for the preparation of enantiomerically pure alcohols and amines.

Authors:  Oscar Verho; Jan-E Bäckvall
Journal:  J Am Chem Soc       Date:  2015-03-19       Impact factor: 15.419

2.  Arylboronic Acid-Catalyzed Racemization of Secondary and Tertiary Alcohols.

Authors:  Gregory R Boyce; Stefania F Musolino; Jianing Yang; Andrew D Smith; James E Taylor
Journal:  J Org Chem       Date:  2022-09-08       Impact factor: 4.198

  2 in total

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