Literature DB >> 12932023

Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H2O2.

Hideki Furutachi1, Mizue Murayama, Amane Shiohara, Satoshi Yamazaki, Shuhei Fujinami, Akira Uehara, Masatatsu Suzuki, Seiji Ogo, Yoshihito Watanabe, Yonezo Maeda.   

Abstract

Reaction of a diiron(III) complex having a xylta4- ligand (N,N,N',N'-m-xylylenediamine tetraacetate) with H2O2 resulted in regioselective hydroxylation of the m-xylyl linker. The reaction mimics the self-hydroxylation of a phenylalanine side chain found for ribonucleotide reductase (R2-W48F/D84E).

Entities:  

Year:  2003        PMID： 12932023     DOI： 10.1039/b304171a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Synthesis, Characterization, and Oxygenation Studies of Carboxylate-Bridged Diiron(II) Complexes with Aromatic Substrates Tethered to Pyridine Ligands and the Formation of a Unique Trinuclear Complex.

Authors:  Simone Friedle; Stephen J Lippard
Journal:  Eur J Inorg Chem       Date:  2009-11-05       Impact factor: 2.524

2.  N,N'-Dicarb-oxy-N,N'-dicarboxyl-ato(m-phenyl-ene)dimethanaminium monohydrate.

Authors:  Yu-Xing Qiang; Shou-Rong Zhu; Min Shao
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-04-22

3.  μ-Oxo-bridged diiron(iii) complexes of tripodal 4N ligands as catalysts for alkane hydroxylation reaction using m-CPBA as an oxidant: substrate vs. self hydroxylation.

Authors:  Mani Balamurugan; Eringathodi Suresh; Mallayan Palaniandavar
Journal:  RSC Adv       Date:  2021-06-17       Impact factor: 3.361
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.