| Literature DB >> 12926955 |
Moballigh Ahmed1, Abdul Majeed Seayad, Ralf Jackstell, Matthias Beller.
Abstract
A highly chemo- and regioselective hydroaminomethylation of simple as well as functionalized alpha-olefins using a cationic rhodium precatalyst together with Xantphos as ligand is reported. Studies of the influence of ligands and reaction conditions led to an unprecedented selective hydroaminomethylation procedure. The novel procedure constitutes an economically attractive and environmentally favorable synthesis of secondary and tertiary aliphatic amines.Entities:
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Year: 2003 PMID： 12926955 DOI： 10.1021/ja030143w
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419