| Literature DB >> 12926920 |
Sung Ok Kang1, José M Llinares, Douglas Powell, David VanderVelde, Kristin Bowman-James.
Abstract
An anion receptor derived from a tren-based amide cryptand with pyridine spacers has been synthesized and characterized. Two crystal structures are reported: the hydrochloride salt and the fluoride complex. The cryptand shows extremely high binding with fluoride ion in DMSO-d6. Both the crystal structure and solution 19F NMR data indicate an encapsulated fluoride ion with very high symmetry.Entities:
Year: 2003 PMID: 12926920 DOI: 10.1021/ja034969+
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419