Literature DB >> 12926387

Does the DABCO-catalysed reaction of 2-hydroxybenzaldehydes with methyl acrylate follow a Baylis-Hillman pathway?

Perry T Kaye1, Musiliyu A Musa, Xolani W Nocanda, Ross S Robinson.   

Abstract

Evidence is presented which supports the intermediacy of dipolar Baylis-Hillman-type adducts in the synthesis of coumarin and chromene derivatives from the reaction of 2-hydroxybenzaldehydes with methyl acrylate in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO).

Entities:  

Year:  2003        PMID: 12926387     DOI: 10.1039/b300360d

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  1 in total

1.  Reactions of salicylaldehyde and enolates or their equivalents: versatile synthetic routes to chromane derivatives.

Authors:  Ishmael B Masesane; Zelalem Yibralign Desta
Journal:  Beilstein J Org Chem       Date:  2012-12-12       Impact factor: 2.883

  1 in total

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