Literature DB >> 12919036

Chemical fixation of carbon dioxide by NaI/PPh3/PhOH.

Jin-Wen Huang1, Min Shi.   

Abstract

In the presence of catalytic amounts of sodium iodide, triphenylphosphine, and phenol, carbon dioxide can efficiently react with epoxides to give the corresponding five-membered cyclic carbonates in high yields. The mechanism of this reaction was disclosed by (31)P NMR spectroscopic data and deuterium labeling experiments.

Entities:  

Year:  2003        PMID： 12919036     DOI： 10.1021/jo0348221

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  4 in total

1.  2,2',2''-Terpyridine-catalyzed synthesis of cyclic carbonates from epoxides and carbon dioxide under solvent-free conditions.

Authors:  Huixin Liu; Renqin Zeng; Ruimao Hua
Journal:  Int J Mol Sci       Date:  2014-06-04       Impact factor: 5.923

2.  On the mechanism of protein supercharging in electrospray ionisation mass spectrometry: Effects on charging of additives with short- and long-chain alkyl constituents with carbonate and sulphite terminal groups.

Authors:  Eric D B Foley; Muhammad A Zenaidee; Rico F Tabor; Junming Ho; Jonathon E Beves; William A Donald
Journal:  Anal Chim Acta X       Date:  2018-12-28

3.  Mechanism of cyclic carbonate synthesis from epoxides and CO2.

Authors:  Michael North; Riccardo Pasquale
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

4.  New Coordination Complexes Based on the 2,6-bis[1-(Phenylimino)ethyl] Pyridine Ligand: Effective Catalysts for the Synthesis of Propylene Carbonates from Carbon Dioxide and Epoxides.

Authors:  Li Xia; Wen-Zhen Wang; Shuang Liu; Xin-Gang Jia; Ying-Hui Zhang; Lei-Lei Li; Ya Wu; Bi-Yun Su; Shu-Bo Geng; Wei Fan
Journal:  Molecules       Date:  2018-09-10       Impact factor: 4.411
  4 in total

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