Literature DB >> 12904005

Unprecedented double C-C bond cleavage of a cyclopentadienyl ligand.

Zhenfeng Xi1, Kimihiko Sato, Ye Gao, Jianming Lu, Tamotsu Takahashi.   

Abstract

Double C-C bond cleavage of a cyclopentadienyl ligand proceeded to titanacyclopentadienes when 2 equiv of nitriles were added and the resulting two-carbon unit and three-carbon unit were converted into a benzene derivative and a pyridine derivative, respectively, in one-pot.

Entities:  

Year:  2003        PMID: 12904005     DOI: 10.1021/ja027234y

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

Review 1.  Multicomponent syntheses of 5- and 6-membered aromatic heterocycles using group 4-8 transition metal catalysts.

Authors:  Daniel N Huh; Yukun Cheng; Connor W Frye; Dominic T Egger; Ian A Tonks
Journal:  Chem Sci       Date:  2021-06-29       Impact factor: 9.825

  1 in total

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