| Literature DB >> 12895064 |
Benoît Laleu1, Christelle Herse, Bo W Laursen, Gérald Bernardinelli, Jérôme Lacour.
Abstract
Chiral acridinium cations, easily prepared by reaction of enantiopure primary amines and tris(2,6-dimethoxy)trityl cation, display restricted rotations around the C(sp(3))-N(sp(2)) bond. A bending of the aromatic backbone and "out-of-plane" displacements of C(9) and N(10) atoms are enforced if bulky amines are introduced.Entities:
Year: 2003 PMID： 12895064 DOI： 10.1021/jo0345998
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354