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Literature DB >> 12876732

Biomimetic hydroxylation of nonactivated CH2 groups with copper complexes and molecular oxygen.

Bruno Schönecker¹, Tatjana Zheldakova, Yong Liu, Manuela Kötteritzsch, Wolfgang Günther, Helmar Görls.

Abstract

Entities: Chemical

Year: 2003 PMID： 12876732 DOI： 10.1002/anie.200250815

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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15 in total

1. Chemical synthesis of 7-oxygenated 12α-hydroxy steroid derivatives to enable the biochemical characterization of cytochrome P450 8B1, the oxysterol 12α-hydroxylase enzyme implicated in cardiovascular health and obesity.

Authors: Samuel D Offei; Hadi D Arman; Mirza Oais Baig; Lazaro S Chavez; Carlos A Paladini; Francis K Yoshimoto
Journal: Steroids Date: 2018-11-03 Impact factor: 2.668

Review 2. Aerobic copper-catalyzed organic reactions.

Authors: Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal: Chem Rev Date: 2013-06-20 Impact factor: 60.622

3. Recent Progress in Steroid Synthesis Triggered by the Emergence of New Catalytic Methods.

Authors: Hem Raj Khatri; Nolan Carney; Ryan Rutkoski; Bijay Bhattarai; Pavel Nagorny
Journal: European J Org Chem Date: 2020-01-01

Review 4. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O₂ Model Systems to Organometallic Transformations.

Authors: Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal: Chem Rev Date: 2019-01-30 Impact factor: 60.622

Biomimetic hydroxylation of nonactivated CH2 groups with copper complexes and molecular oxygen.

1. Chemical synthesis of 7-oxygenated 12α-hydroxy steroid derivatives to enable the biochemical characterization of cytochrome P450 8B1, the oxysterol 12α-hydroxylase enzyme implicated in cardiovascular health and obesity.

Review 2. Aerobic copper-catalyzed organic reactions.

3. Recent Progress in Steroid Synthesis Triggered by the Emergence of New Catalytic Methods.

Review 4. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O₂ Model Systems to Organometallic Transformations.

5. Scalable C-H Oxidation with Copper: Synthesis of Polyoxypregnanes.

6. Methylene C(sp³)-H Arylation of Aliphatic Ketones Using a Transient Directing Group.

7. Copper-Catalyzed Aerobic C-H Trifluoromethylation of Phenanthrolines.

8. Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp³ C-H Bonds.

9. A Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation.

10. Terpenoid-Alkaloids: Their Biosynthetic Twist of Fate and Total Synthesis.

Review 2. Aerobic copper-catalyzed organic reactions.

Review 4. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Review 4. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O₂ Model Systems to Organometallic Transformations.