Literature DB >> 12868947

Grubbs' catalyst in paraffin: an air-stable preparation for alkene metathesis.

Douglass F Taber1, Kevin J Frankowski.   

Abstract

A homogeneous mixture of Grubbs' catalyst in paraffin wax was shown to catalyze three important types of metathesis reactions: ring-closing metathesis, alkene dimerization, and alkene cross-metathesis (e.g., 11 --> 13). This catalyst preparation demonstrated no loss in catalytic activity after 22 months of storage open to the air.

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Year:  2003        PMID: 12868947     DOI: 10.1021/jo030005p

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  8 in total

1.  Activation of C-O and C-N Bonds Using Non-Precious-Metal Catalysis.

Authors:  Timothy B Boit; Ana S Bulger; Jacob E Dander; Neil K Garg
Journal:  ACS Catal       Date:  2020-09-10       Impact factor: 13.084

2.  Breaking Amides using Nickel Catalysis.

Authors:  Jacob E Dander; Neil K Garg
Journal:  ACS Catal       Date:  2017-01-06       Impact factor: 13.084

3.  Potassium hydride in paraffin: a useful base for organic synthesis.

Authors:  Douglass F Taber; Christopher G Nelson
Journal:  J Org Chem       Date:  2006-11-10       Impact factor: 4.354

4.  Benchtop Delivery of Ni(cod)2 using Paraffin Capsules.

Authors:  Jacob E Dander; Nicholas A Weires; Neil K Garg
Journal:  Org Lett       Date:  2016-07-25       Impact factor: 6.005

5.  Ni-Catalyzed Suzuki-Miyaura Cross-Coupling of Aliphatic Amides on the Benchtop.

Authors:  Milauni M Mehta; Timothy B Boit; Jacob E Dander; Neil K Garg
Journal:  Org Lett       Date:  2019-10-17       Impact factor: 6.005

6.  Synthesis of new polyesters by acyclic diene metathesis polymerization of bio-based α,ω-dienes prepared from eugenol and castor oil (undecenoate).

Authors:  Duy Le; Chanatip Samart; Suwadee Kongparakul; Kotohiro Nomura
Journal:  RSC Adv       Date:  2019-04-02       Impact factor: 4.036

7.  Dosage delivery of sensitive reagents enables glove-box-free synthesis.

Authors:  Aaron C Sather; Hong Geun Lee; James R Colombe; Anni Zhang; Stephen L Buchwald
Journal:  Nature       Date:  2015-08-13       Impact factor: 49.962

8.  New indenylidene-type metathesis catalysts bearing unsymmetrical N-heterocyclic ligands with mesityl and nitrobenzyl substituents.

Authors:  Marta Malinowska; Mariana Kozlowska; Agnieszka Hryniewicka; Stanisław Witkowski; Jacek W Morzycki
Journal:  Monatsh Chem       Date:  2016-03-10       Impact factor: 1.451

  8 in total

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