Literature DB >> 12868868

Nickel(0)-mediated sequential addition of carbon dioxide and aryl aldehydes into terminal allenes.

Masanori Takimoto1, Mitsunobu Kawamura, Miwako Mori.   

Abstract

[reaction: see text] Nickel-mediated sequential addition of carbon dioxide and aryl aldehydes into terminal allenes is reported. The reaction proceeded in a diastereoselective manner to afford alpha-methylene-gamma-hydroxy carboxylic acids, which allowed stereoselective preparation of cis-beta, gamma-disubstituted alpha-methylene-gamma-lactones.

Entities:  

Year:  2003        PMID： 12868868     DOI： 10.1021/ol034480l

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  A computational study on the insertion of CO2 into (PSiP)palladium allyl σ-bond.

Authors:  Qin Wang; Cai-Hong Guo; Ying Ren; Hai-Shun Wu
Journal:  J Mol Model       Date:  2015-04-21       Impact factor: 1.810

2.  anti-Aminoallylation of aldehydes via ruthenium-catalyzed transfer hydrogenative coupling of sulfonamido allenes: 1,2-aminoalcohols.

Authors:  Eduardas Skucas; Jason R Zbieg; Michael J Krische
Journal:  J Am Chem Soc       Date:  2009-04-15       Impact factor: 15.419

3.  Alkynes as allylmetal equivalents in redox-triggered C-C couplings to primary alcohols: (Z)-homoallylic alcohols via ruthenium-catalyzed propargyl C-H oxidative addition.

Authors:  Boyoung Y Park; Khoa D Nguyen; Mani Raj Chaulagain; Venukrishnan Komanduri; Michael J Krische
Journal:  J Am Chem Soc       Date:  2014-07-30       Impact factor: 15.419
  3 in total

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