| Literature DB >> 12857070 |
Yasutomo Noishiki1, Hiroko Takami, Yoshiharu Nishiyama, Masahisa Wada, Shigeru Okada, Shigenori Kuga.
Abstract
Crystal conversion of beta-chitin to alpha-chitin by aq. NaOH treatment was studied for a highly crystalline beta-chitin sample from diatom spine. The minimum NaOH concentration to cause swelling was between 25% and 30% w/w. The alkali-swollen material was poorly crystalline and was regenerated as alpha-chitin on washing with water. This conversion caused total collapse of the original microfibrillar morphology. These features are similar to those of 7 N-8 N HCl treatment reported earlier, but alkali treatment was free from depolymerization or deacetylation.Entities:
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Year: 2003 PMID: 12857070 DOI: 10.1021/bm0257513
Source DB: PubMed Journal: Biomacromolecules ISSN: 1525-7797 Impact factor: 6.988