Literature DB >> 12843399

Active nonmetallic Au and Pt species on ceria-based water-gas shift catalysts.

Qi Fu1, Howard Saltsburg, Maria Flytzani-Stephanopoulos.   

Abstract

Traditional analysis of reactions catalyzed by supported metals involves the structure of the metallic particles. However, we report here that for the class of nanostructured gold- or platinum-cerium oxide catalysts, which are active for the water-gas shift reaction, metal nanoparticles do not participate in the reaction. Nonmetallic gold or platinum species strongly associated with surface cerium-oxygen groups are responsible for the activity.

Entities:  

Year:  2003        PMID: 12843399     DOI: 10.1126/science.1085721

Source DB:  PubMed          Journal:  Science        ISSN: 0036-8075            Impact factor:   47.728


  80 in total

1.  Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy.

Authors:  Chunjuan Zhang; Michael E Grass; Anthony H McDaniel; Steven C DeCaluwe; Farid El Gabaly; Zhi Liu; Kevin F McCarty; Roger L Farrow; Mark A Linne; Zahid Hussain; Gregory S Jackson; Hendrik Bluhm; Bryan W Eichhorn
Journal:  Nat Mater       Date:  2010-09-26       Impact factor: 43.841

2.  Catalysis: Tens of thousands of atoms replaced by one.

Authors:  John Meurig Thomas
Journal:  Nature       Date:  2015-09-17       Impact factor: 49.962

3.  Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles.

Authors:  Georgi N Vayssilov; Yaroslava Lykhach; Annapaola Migani; Thorsten Staudt; Galina P Petrova; Nataliya Tsud; Tomáš Skála; Albert Bruix; Francesc Illas; Kevin C Prince; Vladimír Matolín; Konstantin M Neyman; Jörg Libuda
Journal:  Nat Mater       Date:  2011-03-20       Impact factor: 43.841

4.  Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles.

Authors:  Lichen Liu; Avelino Corma
Journal:  Chem Rev       Date:  2018-04-16       Impact factor: 60.622

5.  Counting electrons on supported nanoparticles.

Authors:  Yaroslava Lykhach; Sergey M Kozlov; Tomáš Skála; Andrii Tovt; Vitalii Stetsovych; Nataliya Tsud; Filip Dvořák; Viktor Johánek; Armin Neitzel; Josef Mysliveček; Stefano Fabris; Vladimír Matolín; Konstantin M Neyman; Jörg Libuda
Journal:  Nat Mater       Date:  2015-12-14       Impact factor: 43.841

Review 6.  Catalysis by clusters with precise numbers of atoms.

Authors:  Eric C Tyo; Stefan Vajda
Journal:  Nat Nanotechnol       Date:  2015-07       Impact factor: 39.213

7.  Ligand Fluorination to Optimize Preferential Oxidation (PROX) of Carbon Monoxide by Water-Soluble Rhodium Porphyrins.

Authors:  Justin C Biffinger; Shriharsha Uppaluri; Haoran Sun; Stephen G Dimagno
Journal:  ACS Catal       Date:  2011-05-18       Impact factor: 13.084

8.  Theoretical study of CO oxidation on cationic, neutral, and anionic AuM dimers (M = Pd and Ag).

Authors:  Xuan Chen; Rui-Feng Lu; Er-Jun Kan; Yu-Zhen Liu; Chuan-Yun Xiao; Kai-Ming Deng
Journal:  J Mol Model       Date:  2014-06-05       Impact factor: 1.810

9.  Recent Progress in Syntheses and Applications of Dumbbell-like Nanoparticles.

Authors:  Chao Wang; Chenjie Xu; Hao Zeng; Shouheng Sun
Journal:  Adv Mater       Date:  2009       Impact factor: 30.849

10.  High catalytic activity of Au/CeOx/TiO2(110) controlled by the nature of the mixed-metal oxide at the nanometer level.

Authors:  Joon B Park; Jesus Graciani; Jaime Evans; Dario Stacchiola; Shuguo Ma; Ping Liu; Akira Nambu; Javier Fernández Sanz; Jan Hrbek; José A Rodriguez
Journal:  Proc Natl Acad Sci U S A       Date:  2009-03-10       Impact factor: 11.205

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