Literature DB >> 12841248

[60]- and [70]Fullerenes are trifluoromethylated across 5:6-bonds.

Adam D Darwish1, Anthony G Avent, Ala'a K Abdul-Sada, Roger Taylor.   

Abstract

Trifluoromethylation of [60]- and [70]fullerenes occurs across both 6:6- and 5:6-bonds giving unsymmetrical tetramethyl adducts having four contiguous CF3 groups; both fullerenes give bis adducts which do not involve 6:6-addition, and unsymmetrical hexa-adducts (with contiguous CF3 groups) are also obtained from [60]fullerene.

Entities:  

Year:  2003        PMID: 12841248     DOI: 10.1039/b303496h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Determining addition pathways and stable isomers for CF3 functionalization of endohedral Gd@C60.

Authors:  Chris Ewels; Jeremy Rio; Hiroyuki Niwa; Haruka Omachi; Hisanori Shinohara; Mark Rayson; Patrick Briddon
Journal:  R Soc Open Sci       Date:  2018-09-05       Impact factor: 2.963

  1 in total

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