| Literature DB >> 12839481 |
Philippe Renaud1, Cyril Ollivier, Valéry Weber.
Abstract
B-Alkylcatecholboranes, prepared by rhodium(I)-catalyzed hydroboration of alkenes, are suitable radical precursors for conjugate addition to activated olefins. This procedure proved to be particularly useful for the control of the regio- and chemoselectivity of such tandem processes. Enantioselective hydroboration has also been successfully coupled with radical chain reaction in a one-pot process.Entities:
Year: 2003 PMID： 12839481 DOI： 10.1021/jo034515v
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354