Literature DB >> 12816447

Evidence for the involvement of silver nanoclusters during the Wolff rearrangement of alpha-diazoketones.

Surendra G Sudrik1, Trupti Maddanimath, Nirmalya K Chaki, Sambhaji P Chavan, Subhash P Chavan, Harikisan R Sonawane, K Vijayamohanan.   

Abstract

In situ-generated silver nanoclusters(Ag(n)) during the reduction of either silver(I) oxide or other salts presumably catalyze the Wolff rearrangement of alpha-diazoketones. Their optical, physical, and catalytic properties depend on the starting silver(I) compound and the reaction conditions. [reaction: see text]

Entities:  

Year:  2003        PMID： 12816447     DOI： 10.1021/ol034747g

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Chemical Synthesis of Complex Molecules Using Nanoparticle Catalysis.

Authors:  Huan Cong; John A Porco
Journal:  ACS Catal       Date:  2012-01-01       Impact factor: 13.084

2.  Structural characterization of an enantiomerically pure amino acid imidazolide and direct formation of the beta-lactam nucleus from an alpha-amino acid.

Authors:  Brian S Gerstenberger; Jinzhen Lin; Yvette S Mimieux; Lauren E Brown; Allen G Oliver; Joseph P Konopelski
Journal:  Org Lett       Date:  2008-01-09       Impact factor: 6.005
  2 in total

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