Literature DB >> 12816419

Unusual reaction of beta-hydroxy alpha-diazo carbonyl compounds with Cl3CCN/NaH and Rh(II)-catalyzed reaction of beta-trichloroacetylamino alpha-diazo carbonyl compounds.

Weifeng Shi1, Nan Jiang, Shiwei Zhang, Weiming Wu, Daming Du, Jianbo Wang.   

Abstract

The hydroxyl group was directly converted into the trichloroacetylamino group by reacting beta-hydroxy alpha-diazo carbonyl compounds with Cl(3)CCN and NaH. Rh(II)-catalyzed reactions of the beta-amino alpha-diazo carbonyl compounds were discussed. [reaction: see text]

Entities:  

Year:  2003        PMID： 12816419     DOI： 10.1021/ol034550o

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Rearrangement of Benzylic Trichloroacetimidates to Benzylic Trichloroacetamides.

Authors:  Arijit A Adhikari; Tamie Suzuki; Reesheda T Gilbert; Matthew R Linaburg; John D Chisholm
Journal:  J Org Chem       Date:  2017-03-27       Impact factor: 4.354

2.  Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.

Authors:  Xichen Xu; Yu Qian; Peter Y Zavalij; Michael P Doyle
Journal:  J Am Chem Soc       Date:  2013-01-17       Impact factor: 15.419

3.  Pyridine group assisted addition of diazo-compounds to imines in the 3-CC reaction of 2-aminopyridines, aldehydes, and diazo-compounds.

Authors:  Anton V Gulevich; Victoria Helan; Donald J Wink; Vladimir Gevorgyan
Journal:  Org Lett       Date:  2013-02-01       Impact factor: 6.005
  3 in total

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