Literature DB >> 12812484

A reversible valence equilibrium in a heavier main group compound.

Andrew D Phillips1, Shirley Hino, Philip P Power.   

Abstract

The addition of LiPh to Ar*SnCl (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-iPr3) at low temperature afforded the Sn(1)-Sn(III) species Ar*SnSnPh2Ar*, which exists in equilibrium with the Sn(II) compound Ar*SnPh. It is the first example of a room-temperature equilibrium of compounds involving main group elements in different oxidation states.

Entities:  

Year:  2003        PMID: 12812484     DOI: 10.1021/ja0347843

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

1.  A cyclic disilylated stannylene: synthesis, dimerization, and adduct formation.

Authors:  Henning Arp; Judith Baumgartner; Christoph Marschner; Thomas Müller
Journal:  J Am Chem Soc       Date:  2011-03-25       Impact factor: 15.419

  1 in total

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