Literature DB >> 12797767

Catalytic activity of supported Au nanoparticles deposited from block copolymer micelles.

Thomas F Jaramillo1, Sung-Hyeon Baeck, Beatriz Roldan Cuenya, Eric W McFarland.   

Abstract

Quasi-ordered, highly dispersed, gold nanoclusters of tightly controlled particle size were synthesized by dip-coating substrates with gold precursors encapsulated by block-copolymer micelles. By this method, gold particles (4.8 +/- 1.3 nm) were deposited on ITO-coated glass and shown to be catalytically active for electro-oxidation of carbon monoxide. XPS confirmed the catalytically active particles were predominantly Au0; however, a large fraction existed as Au3+. Whereas bulk gold is inert, these results demonstrate that catalytically active Au nanoparticles can be derived from micelle encapsulation.

Entities:  

Year:  2003        PMID: 12797767     DOI: 10.1021/ja029800v

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  14 in total

1.  Scanning probe block copolymer lithography.

Authors:  Jinan Chai; Fengwei Huo; Zijian Zheng; Louise R Giam; Wooyoung Shim; Chad A Mirkin
Journal:  Proc Natl Acad Sci U S A       Date:  2010-11-08       Impact factor: 11.205

2.  Synthesis and characterization of bicontinuous cubic poly(3,4-ethylene dioxythiophene) gyroid (PEDOT GYR) gels.

Authors:  Whirang Cho; Jinghang Wu; Bong Sup Shim; Wei-Fan Kuan; Sarah E Mastroianni; Wen-Shiue Young; Chin-Chen Kuo; Thomas H Epps; David C Martin
Journal:  Phys Chem Chem Phys       Date:  2015-02-21       Impact factor: 3.676

3.  Gold Chain Formation via Local Lifting of Surface Reconstruction by Hot Electron Injection on H2(D2)/Au(111).

Authors:  P Merino; A Rosławska; A Grewal; C C Leon; C Gonzalez; K Kuhnke; K Kern
Journal:  ACS Nano       Date:  2020-10-29       Impact factor: 15.881

Review 4.  Block Copolymer Template-Directed Catalytic Systems: Recent Progress and Perspectives.

Authors:  Labeesh Kumar; Sajan Singh; Andriy Horechyy; Andreas Fery; Bhanu Nandan
Journal:  Membranes (Basel)       Date:  2021-04-27

5.  Manipulation of gold colloidal nanoparticles with atomic force microscopy in dynamic mode: influence of particle-substrate chemistry and morphology, and of operating conditions.

Authors:  Samer Darwich; Karine Mougin; Akshata Rao; Enrico Gnecco; Shrisudersan Jayaraman; Hamidou Haidara
Journal:  Beilstein J Nanotechnol       Date:  2011-02-04       Impact factor: 3.649

6.  Gold-ionic liquid nanofluids with preferably tribological properties and thermal conductivity.

Authors:  Baogang Wang; Xiaobo Wang; Wenjing Lou; Jingcheng Hao
Journal:  Nanoscale Res Lett       Date:  2011-03-28       Impact factor: 4.703

7.  Effect of Au nano-particle aggregation on the deactivation of the AuCl3/AC catalyst for acetylene hydrochlorination.

Authors:  Bin Dai; Qinqin Wang; Feng Yu; Mingyuan Zhu
Journal:  Sci Rep       Date:  2015-05-21       Impact factor: 4.379

8.  A self-supporting bimetallic Au@Pt core-shell nanoparticle electrocatalyst for the synergistic enhancement of methanol oxidation.

Authors:  Changhui Tan; Yinghui Sun; Jianzhong Zheng; Dan Wang; Ziyang Li; Huajie Zeng; Jun Guo; Liqiang Jing; Lin Jiang
Journal:  Sci Rep       Date:  2017-07-24       Impact factor: 4.379

9.  In vivo self-bio-imaging of tumors through in situ biosynthesized fluorescent gold nanoclusters.

Authors:  Jianling Wang; Gen Zhang; Qiwei Li; Hui Jiang; Chongyang Liu; Christian Amatore; Xuemei Wang
Journal:  Sci Rep       Date:  2013-01-29       Impact factor: 4.379

10.  Efficient Dual-Site Carbon Monoxide Electro-Catalysts via Interfacial Nano-Engineering.

Authors:  Zhen Liu; Zhongyuan Huang; Feifei Cheng; Zhanhu Guo; Guangdi Wang; Xu Chen; Zhe Wang
Journal:  Sci Rep       Date:  2016-09-21       Impact factor: 4.379

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