Literature DB >> 12790623

Sulfinyl moiety as an internal nucleophile. 1. Efficient stereoselective synthesis of fragment a of cryptophycin 3.

Sadagopan Raghavan1, K A Tony.   

Abstract

A novel, efficient, and stereoselective synthesis of fragment A of cryptophycin 3 is disclosed. The key step involves the regio- and stereoselective transformation of an unsaturated ester to a bromohydrin via anchimeric assistance by the sulfinyl group.

Entities:  

Mesh：

Substances：

Year:  2003        PMID： 12790623     DOI： 10.1021/jo026802p

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Enantioselective approach to quinolizidines: total synthesis of cermizine D and formal syntheses of senepodine G and cermizine C.

Authors:  Nagarathanam Veerasamy; Erik C Carlson; Nathan D Collett; Mrinmoy Saha; Rich G Carter
Journal:  J Org Chem       Date:  2013-04-29       Impact factor: 4.354

2.  Expedient enantioselective synthesis of cermizine D.

Authors:  Nagarathanam Veerasamy; Erik C Carlson; Rich G Carter
Journal:  Org Lett       Date:  2012-02-28       Impact factor: 6.005
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.