Literature DB >> 12790622

Trichloroisocyanuric/TEMPO oxidation of alcohols under mild conditions: a close investigation.

Lidia De Luca1, Giampaolo Giacomelli, Simonetta Masala, Andrea Porcheddu.   

Abstract

Efficient oxidation of primary alcohols to the corresponding carboxylic acids can be carried out at room temperature and in acetone/water, using trichloroisocyanuric acid (TCCA) in the presence of catalytic TEMPO. The mild conditions of this procedure and the total absence of any transition metal make this reaction suitable for safe laboratory use. A possible mechanism is presented and discussed.

Entities:  

Year:  2003        PMID： 12790622     DOI： 10.1021/jo034276b

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  6 in total

1.  FeO(OH)@C-Catalyzed Selective Hydrazine Substitution of p-Nitro-Aryl Fluorides and their Application for the Synthesis of Phthalazinones.

Authors:  Dingzhong Li; Wensheng Zhang; Longzhi Zhu; Shuang-Feng Yin; Nobuaki Kambe; Renhua Qiu
Journal:  ChemistryOpen       Date:  2022-05       Impact factor: 2.630

2.  Synthesis of β-C-galactosyl D- and L-alanines.

Authors:  V Narasimharao Thota; Jacquelyn Gervay-Hague; Suvarn S Kulkarni
Journal:  Org Biomol Chem       Date:  2012-10-28       Impact factor: 3.876

3.  2-Deoxystreptamine Conjugates by Truncation-Derivatization of Neomycin.

Authors:  M Waqar Aslam; Leandro C Tabares; Alessio Andreoni; Gerard W Canters; Floris P J T Rutjes; Floris L Van Delft
Journal:  Pharmaceuticals (Basel)       Date:  2010-03-15

4.  Preparation of Functional Monomers as Precursors of Bioprobes from a Common Styrene Derivative and Polymer Synthesis.

Authors:  Riho Hayama; Tetsuo Koyama; Takahiko Matsushita; Ken Hatano; Koji Matsuoka
Journal:  Molecules       Date:  2018-11-04       Impact factor: 4.411

5.  Synthesis of Acids and Amino Acids by Selective Oxidation of Primary Hydroxyl Groups to Carboxylic acids in Sugars.

Authors:  Natarajan Raju; Rolf E Swenson
Journal:  Int J Chem       Date:  2021-06-30

6.  De novo synthesis of D- and L-fucosamine containing disaccharides.

Authors:  Daniele Leonori; Peter H Seeberger
Journal:  Beilstein J Org Chem       Date:  2013-02-14       Impact factor: 2.883
  6 in total

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