Literature DB >> 12790618

Regiospecificity in the synthesis of diaryl sulfones.

Daniel E Allgeier1, Sue Ann Herbert, Rory Nee, Kenneth D Schlecht, K Thomas Finley.   

Abstract

The addition of arylsulfinic acids to 2-methyl-1,4-benzoquinone provides high yields of sulfones in a wide variety of solvents. The distribution of isomeric products obtained is strongly influenced by either (1) the acidity of aqueous solvents or (2) the water content of alcohol solvents. The distribution of isomeric products does not change in the various anhydrous, aprotic solvents examined.

Entities:  

Year:  2003        PMID: 12790618     DOI: 10.1021/jo026640x

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Oxidative radical coupling of hydroquinones and thiols using chromic acid: one-pot synthesis of quinonyl alkyl/aryl thioethers.

Authors:  T P Adarsh Krishna; Sakthivel Pandaram; Suresh Chinnasamy; Andivelu Ilangovan
Journal:  RSC Adv       Date:  2020-05-21       Impact factor: 4.036

  1 in total

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