Literature DB >> 12786203

Continuous demixing at liquid-vapor coexistence in a symmetrical binary fluid mixture.

Nigel B Wilding1.   

Abstract

We report a Monte Carlo finite-size scaling study of the demixing transition of a symmetrical Lennard-Jones binary fluid mixture. For equal concentration of species, and for a choice of the unlike-to-like interaction ratio delta=0.7, this transition is found to be continuous at liquid-vapor coexistence. The associated critical end point exhibits an Ising-like universality. These findings confirm those of earlier smaller scale simulation studies of the same model, but contradict the findings of recent integral equation and hierarchical reference theory investigations.

Year:  2003        PMID: 12786203     DOI: 10.1103/PhysRevE.67.052503

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  1 in total

1.  Solubility Limits in Lennard-Jones Mixtures: Effects of Disparate Molecule Geometries.

Authors:  Kippi M Dyer; John S Perkyns; B Montgomery Pettitt
Journal:  J Phys Chem B       Date:  2015-02-19       Impact factor: 2.991

  1 in total

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