Literature DB >> 12778716

A stable alkyl hydride of a first row transition metal.

Leonard A MacAdams1, Gerald P Buffone, Christopher D Incarvito, James A Golen, Arnold L Rheingold, Klaus H Theopold.   

Abstract

Hydrogenolysis of a Cr(III) dialkyl precursor produced a binuclear chromium complex with a bridging hydride and a bridging alkyl; this structurally characterized organometallic compound is thermally very stable and does not undergo the expected reductive elimination of alkane.

Entities:  

Year:  2003        PMID： 12778716     DOI： 10.1039/b301943h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  New Routes to Low-Coordinate Iron Hydride Complexes: The Binuclear Oxidative Addition of H(2).

Authors:  Thomas R Dugan; Patrick L Holland
Journal:  J Organomet Chem       Date:  2009-08       Impact factor: 2.369

2.  Bis[μ-N,N'-bis(2,6-diisopropylphenyl)ethene-1,2-diamido]-1,4(η);1:2κN:N;3:4κN:N-bis(diethyl ether)-1κO,4κO-di-μ-hydrido-2:3κH:H-2,3-dichromium(II)-1,4-dilithium(I) pentane hemisolvate.

Authors:  Stephan Peitz; Normen Peulecke; Bernd H Müller; Anke Spannenberg; Uwe Rosenthal
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-02-13
  2 in total

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