Literature DB >> 12746811

Catalytic synthesis of ammonia-a "never-ending story"?

Robert Schlögl1.   

Abstract

Nitrogen atoms are essential for the function of biological molecules and thus are and important component of fertilizers and medicaments. Bonds to nitrogen also find nonbiological uses in dyes, explosives, and resins. The synthesis of all these materials requires ammonia as an activated nitrogen building block. This situation is true for natural processes and the chemical industry. Knowledge of the various techniques for the preparation of ammonia is thus of fundamental importance for chemistry. The Haber-Bosch synthesis was the first heterogeneous catalytic system employed in the chemical industry and is still in use today. Understanding the mechanism and the translation of the knowledge into technical perfection has become a fundamental criterion for scientific development in catalysis research.

Entities:  

Year:  2003        PMID: 12746811     DOI: 10.1002/anie.200301553

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  46 in total

Review 1.  Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Authors:  Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal:  Chem Rev       Date:  2020-04-30       Impact factor: 60.622

2.  N-H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe-N2 and Fe-CN Reductions.

Authors:  Jonathan Rittle; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2017-02-17       Impact factor: 15.419

Review 3.  Biosynthesis of nitrogenase metalloclusters.

Authors:  Markus W Ribbe; Yilin Hu; Keith O Hodgson; Britt Hedman
Journal:  Chem Rev       Date:  2013-12-13       Impact factor: 60.622

4.  Evaluation of the Catalytic Relevance of the CO-Bound States of V-Nitrogenase.

Authors:  Chi Chung Lee; Jarett Wilcoxen; Caleb J Hiller; R David Britt; Yilin Hu
Journal:  Angew Chem Int Ed Engl       Date:  2018-03-01       Impact factor: 15.336

5.  Density functional theory in surface chemistry and catalysis.

Authors:  Jens K Nørskov; Frank Abild-Pedersen; Felix Studt; Thomas Bligaard
Journal:  Proc Natl Acad Sci U S A       Date:  2011-01-10       Impact factor: 11.205

6.  Vanadium nitrogenase reduces CO.

Authors:  Chi Chung Lee; Yilin Hu; Markus W Ribbe
Journal:  Science       Date:  2010-08-06       Impact factor: 47.728

7.  Ammonia Synthesis at Low Pressure.

Authors:  Edward Cussler; Alon McCormick; Michael Reese; Mahdi Malmali
Journal:  J Vis Exp       Date:  2017-08-23       Impact factor: 1.355

8.  Closed-shell and open-shell square-planar iridium nitrido complexes.

Authors:  Markus G Scheibel; Bjorn Askevold; Frank W Heinemann; Edward J Reijerse; Bas de Bruin; Sven Schneider
Journal:  Nat Chem       Date:  2012-06-03       Impact factor: 24.427

9.  Complete cleavage of the N≡N triple bond by Ta2N+ via degenerate ligand exchange at ambient temperature: A perfect catalytic cycle.

Authors:  Caiyun Geng; Jilai Li; Thomas Weiske; Helmut Schwarz
Journal:  Proc Natl Acad Sci U S A       Date:  2019-10-07       Impact factor: 11.205

10.  Ta2 +-mediated ammonia synthesis from N2 and H2 at ambient temperature.

Authors:  Caiyun Geng; Jilai Li; Thomas Weiske; Helmut Schwarz
Journal:  Proc Natl Acad Sci U S A       Date:  2018-10-23       Impact factor: 11.205

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