Literature DB >> 12744326

A free radical initiated optically active vinyl polymer with memory of chirality after removal of the inducing stereogenic center.

Zhenning Yu1, Xinhua Wan, Hailiang Zhang, Xiaofang Chen, Qifeng Zhou.   

Abstract

Free radical polymerization of (+)-2,5-bis[4'-((S)-2-methylbutyloxy)phenyl]styrene yields a chiral polymer with memory of optical activity after the initial stereogenic center in the side group of the monomer is chemically removed.

Entities:  

Year:  2003        PMID： 12744326     DOI： 10.1039/b212916g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Synthesis of stable and soluble one-handed helical homopoly(substituted acetylene)s without the coexistence of any other chiral moieties via two-step polymer reactions in membrane state: molecular design of the starting monomer.

Authors:  Yunosuke Abe; Toshiki Aoki; Hongge Jia; Shingo Hadano; Takeshi Namikoshi; Yuriko Kakihana; Lijia Liu; Yu Zang; Masahiro Teraguchi; Takashi Kaneko
Journal:  Molecules       Date:  2012-01-04       Impact factor: 4.411
  1 in total

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