Literature DB >> 12739666

A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system.

Hajime Kawanami1, Akiyoshi Sasaki, Keitaro Matsui, Yutaka Ikushima.   

Abstract

The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.

Entities:  

Year:  2003        PMID： 12739666     DOI： 10.1039/b212823c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Theoretical investigation of the mechanism for the cycloaddition of CO2 to epoxides catalyzed by a magnesium(II) porphyrin complex.

Authors:  Qin Wang; Cai-Hong Guo; Jianfeng Jia; Hai-Shun Wu
Journal:  J Mol Model       Date:  2015-06-26       Impact factor: 1.810

2.  2,2',2''-Terpyridine-catalyzed synthesis of cyclic carbonates from epoxides and carbon dioxide under solvent-free conditions.

Authors:  Huixin Liu; Renqin Zeng; Ruimao Hua
Journal:  Int J Mol Sci       Date:  2014-06-04       Impact factor: 5.923

3.  Heterogeneous photocatalytic performances of CO2 reduction based on the [Emim]BF4 + TEOA + H2O system.

Authors:  Jinliang Lin; Youfeng Li; Bo Xie
Journal:  RSC Adv       Date:  2019-11-04       Impact factor: 4.036

4.  Highly efficient Co centers functionalized by nitrogen-doped carbon for the chemical fixation of CO2.

Authors:  Yuying Yang; Hong Li; Supeng Pei; Feng Liu; Wei Feng; Yongming Zhang
Journal:  RSC Adv       Date:  2020-11-23       Impact factor: 4.036

5.  Immobilization of Ionic Liquid on a Covalent Organic Framework for Effectively Catalyzing Cycloaddition of CO2 to Epoxides.

Authors:  Qianqian Yan; Hao Liang; Shenglin Wang; Hui Hu; Xiaofang Su; Songtao Xiao; Huanjun Xu; Xuechao Jing; Fei Lu; Yanan Gao
Journal:  Molecules       Date:  2022-09-21       Impact factor: 4.927
  5 in total

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