| Literature DB >> 12713306 |
Eric J Tisdale1, Hongmei Li, Binh G Vong, Sun Hee Kim, Emmanuel A Theodorakis.
Abstract
An efficient synthetic approach to the tricyclic core 8 of lateriflorone is described. Essential to the synthesis was the implementation of a biomimetic tandem Claisen/Diels-Alder reaction that produced the desired tricyclic scaffold as a single isomer. A rationalization of the excellent regio and stereoselectivity of this transformation is also proposed. [reaction: see text]Entities:
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Year: 2003 PMID： 12713306 DOI： 10.1021/ol034276y
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005