Literature DB >> 12713304

New process for the preparation of methyl carbonates.

Peter G M Wuts1, Scott W Ashford, Andrew M Anderson, Joseph R Atkins.   

Abstract

The methyl carbonate of HOBt was developed for the conversion of alcohols to carbonates. This method is superior to the use of methyl chloroformate or methyl pyrocarbonate, especially with more hindered alcohols. The reagent is a stable solid that is easily prepared on a multigram scale. [reaction: see text]

Entities:  

Year:  2003        PMID: 12713304     DOI: 10.1021/ol034274d

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Synthesis of skeletally diverse alkaloid-like molecules: exploitation of metathesis substrates assembled from triplets of building blocks.

Authors:  Sushil K Maurya; Mark Dow; Stuart Warriner; Adam Nelson
Journal:  Beilstein J Org Chem       Date:  2013-04-22       Impact factor: 2.883

  1 in total

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