Literature DB >> 12703807

The first example of direct oxidation of sulfides to sulfones by an osmate molecular oxygen system.

Boyapati M Choudary1, Chinta Reddy V Reddy, Billakanti V Prakash, Mannepalli L Kantam, B Sreedhar.   

Abstract

Osmate-exchanged Mg-Al layered double hydroxides catalysed the delivery of two oxygen atoms simultaneously via a 3 + 1 cycloaddition to sulfide to form sulfone directly for the first time, reminiscent of 3 + 2 cycloaddition in asymmetric dihydroxylation reactions.

Entities:  

Year:  2003        PMID: 12703807

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Sulfide Oxidation by O2: Synthesis, Structure and Reactivity of Novel Sulfide-Incorporated Fe(II) Bis(imino)pyridine Complexes.

Authors:  Leland R Widger; Maxime A Siegler; David P Goldberg
Journal:  Polyhedron       Date:  2013-07-13       Impact factor: 3.052

  1 in total

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