| Literature DB >> 12670204 |
Kee-Chan Kim1, Frank Hauke, Andreas Hirsch, Peter D W Boyd, Elizabeth Carter, Robert S Armstrong, Peter A Lay, Christopher A Reed.
Abstract
A heterofullerene isoelectronic to C60 is reported. The azafullerenium cation C59N+ can be isolated in good yield as a carborane salt via the two-electron oxidation of the C-C bond of (C59N)2 dimer. [C59N][Ag(CB11H6Cl6)2] has been characterized by electronic, IR, Raman, and 13C NMR spectroscopies, MALDI spectrometry, DFT calculations, and X-ray crystallography.Entities:
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Year: 2003 PMID： 12670204 DOI： 10.1021/ja034014r
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419