| Literature DB >> 12659593 |
Lionel Gentric1, Issam Hanna, Louis Ricard.
Abstract
[reaction: see text] An efficient entry to the fully elaborated skeleton of vinigrol is described. The installation of the desired stereochemistry at C(12) and the construction of the eight-membered ring were achieved in one operation by a remarkably facile anionic oxy-Cope rearrangement of Z-isopropenyl isomer 24.Entities:
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Year: 2003 PMID: 12659593 DOI: 10.1021/ol034217k
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005