Literature DB >> 12659585

New Fe(III)-mediated radical cascade reactions of cyclopropyl silyl ethers.

Kevin I Booker-Milburn1, J Leighton Jones, Graham E M Sibley, Richard Cox, Jim Meadows.   

Abstract

[reaction: see text] Fe(III)-mediated ring opening of cyclopropyl ethers bearing a phenyl-substituted butenyl side chain leads to the generation of beta-keto radicals that undergo 5-exo cyclization followed by a novel cascade sequence resulting in the formation of tricyclic ethers.

Entities:  

Year:  2003        PMID: 12659585     DOI: 10.1021/ol0341703

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Iron-catalysed, general and operationally simple formal hydrogenation using Fe(OTf)3 and NaBH4.

Authors:  Alistair J MacNair; Ming-Ming Tran; Jennifer E Nelson; G Usherwood Sloan; Alan Ironmonger; Stephen P Thomas
Journal:  Org Biomol Chem       Date:  2014-07-28       Impact factor: 3.876

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.