Literature DB >> 12638851

The nature of the colloidal 'glass' transition.

Kenneth A Dawson1, A Lawlor, Paolo DeGregorio, Gavin D McCullagh, Emanuela Zaccarelli, Giuseppe Foffi, Piero Tartaglia.   

Abstract

The dynamically arrested state of matter is discussed in the context of athermal systems, such as the hard sphere colloidal arrest. We believe that the singular dynamical behaviour near arrest expressed, for example, in how the diffusion constant vanishes may be 'universal', in a sense to be discussed in the paper. Based on this we argue the merits of studying the problem with simple lattice models. This, by analogy with the the critical point of the Ising model, should lead us to clarify the questions, and begin the program of establishing the degree of universality to be expected. We deal only with 'ideal' athermal dynamical arrest transitions, such as those found for hard sphere systems. However, it is argued that dynamically available volume (DAV) is the relevant order parameter of the transition, and that universal mechanisms may be well expressed in terms of DAV. For simple lattice models we give examples of simple laws that emerge near the dynamical arrest, emphasising the idea of a near-ideal gas of 'holes', interacting to give the power law diffusion constant scaling near the arrest. We also seek to open the discussion of the possibility of an underlying weak coupling theory of the dynamical arrest transition, based on DAV.

Entities:  

Year:  2003        PMID: 12638851     DOI: 10.1039/b204624e

Source DB:  PubMed          Journal:  Faraday Discuss        ISSN: 1359-6640            Impact factor:   4.008


  2 in total

1.  Exact solution of a jamming transition: closed equations for a bootstrap percolation problem.

Authors:  Paolo De Gregorio; Aonghus Lawlor; Phil Bradley; Kenneth A Dawson
Journal:  Proc Natl Acad Sci U S A       Date:  2005-04-04       Impact factor: 11.205

2.  The nonequilibrium phase and glass transition behavior of beta-lactoglobulin.

Authors:  Roger Parker; Timothy R Noel; Geoffrey J Brownsey; Katrin Laos; Stephen G Ring
Journal:  Biophys J       Date:  2005-05-27       Impact factor: 4.033

  2 in total

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