Literature DB >> 12617647

A titanium-catalyzed three-component coupling to generate alpha,beta-unsaturated beta-iminoamines.

Changsheng Cao1, Yanhui Shi, Aaron L Odom.   

Abstract

The three-component coupling of an amine, alkyne, and isonitrile is facilitated by a titanium complex bearing the N,N-di(pyrrolyl-alpha-methyl)-N-methylamine (dpma) ligand. From this methodology, alpha,beta-unsaturated beta-iminoamines are generated regioselectively with many substrates and are available on multigram scales.

Entities:  

Year:  2003        PMID： 12617647     DOI： 10.1021/ja0284714

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  Carboamination: additions of imine C=N bonds across alkynes catalyzed by imidozirconium complexes.

Authors:  Rebecca T Ruck; Rebecca L Zuckerman; Shane W Krska; Robert G Bergman
Journal:  Angew Chem Int Ed Engl       Date:  2004-10-11       Impact factor: 15.336

2.  Self-Assembly of a Library of Polyborate Chiral Anions for Asymmetric Catalytic Quinoline Reduction.

Authors:  Aman A Desai; Yong Guan; Aaron L Odom; Supriyo Majumder; William D Wulff
Journal:  Tetrahedron Lett       Date:  2015-06-03       Impact factor: 2.415

3.  Ti-Catalyzed and -Mediated Oxidative Amination Reactions.

Authors:  Ian A Tonks
Journal:  Acc Chem Res       Date:  2021-08-22       Impact factor: 24.466

4.  Catalytic Isonitrile Insertions and Condensations Initiated by RNC-X Complexation.

Authors:  Suravi Chakrabarty; Shruti Choudhary; Arpit Doshi; Fa-Qiang Liu; Rishabh Mohan; Manasa P Ravindra; Dhruv Shah; Xun Yang; Fraser F Fleming
Journal:  Adv Synth Catal       Date:  2014-06-20       Impact factor: 5.837

5.  Reactivity of terminal imido complexes of group 4-6 metals: stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules.

Authors:  Kento Kawakita; Yuya Kakiuchi; Hayato Tsurugi; Kazushi Mashima; Bernard F Parker; John Arnold; Ian A Tonks
Journal:  Coord Chem Rev       Date:  2020-01-14       Impact factor: 22.315

6.  Multicomponent Pyrazole Synthesis from Alkynes, Nitriles, and Titanium Imido Complexes via Oxidatively Induced N-N Bond Coupling.

Authors:  Adam J Pearce; Robin P Harkins; Benjamin R Reiner; Alexander C Wotal; Rachel J Dunscomb; Ian A Tonks
Journal:  J Am Chem Soc       Date:  2020-02-20       Impact factor: 15.419

7.  α-Diimine synthesis via titanium-mediated multicomponent diimination of alkynes with C-nitrosos.

Authors:  Connor W Frye; Dominic T Egger; Errikos Kounalis; Adam J Pearce; Yukun Cheng; Ian A Tonks
Journal:  Chem Sci       Date:  2021-12-27       Impact factor: 9.825
  7 in total

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