Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 C-H activation of imidazolium salts by Pt(0) at ambient temperature: synthesis of hydrido platinum bis(carbene) compounds.

Literature DB >> 12613632

C-H activation of imidazolium salts by Pt(0) at ambient temperature: synthesis of hydrido platinum bis(carbene) compounds.

Marcel A Duin¹, Nicolas D Clement, Kingsley J Cavell, Cornelis J Elsevier.

Abstract

A zerovalent platinum(carbene) complex with two monoalkene ligands, which is able to activate C-H bonds of imidazolium salts at room temperature to yield isolable hydrido platinum(II) bis(carbene) compounds, has been synthesised for the first time.

Entities: Chemical

Year: 2003 PMID： 12613632 DOI： 10.1039/b211235c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

3 in total

1. Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts.

Authors: Rodolphe Jazzar; Jean-Baptiste Bourg; Rian D Dewhurst; Bruno Donnadieu; Guy Bertrand
Journal: J Org Chem Date: 2007-04-05 Impact factor: 4.354

2. A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds.

Authors: Rodolphe Jazzar; Hongze Liang; Bruno Donnadieu; Guy Bertrand
Journal: J Organomet Chem Date: 2006 Impact factor: 2.369

3. Experimental and Theoretical Study of Ni^II - and Pd^II -Promoted Double Geminal C(sp³ )-H Bond Activation Providing Facile Access to NHC Pincer Complexes: Isolated Intermediates and Mechanism.

Authors: Fengkai He; Christophe Gourlaouen; Huan Pang; Pierre Braunstein
Journal: Chemistry Date: 2022-06-13 Impact factor: 5.020

3 in total

C-H activation of imidazolium salts by Pt(0) at ambient temperature: synthesis of hydrido platinum bis(carbene) compounds.

1. Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts.

2. A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds.

3. Experimental and Theoretical Study of NiII - and PdII -Promoted Double Geminal C(sp3 )-H Bond Activation Providing Facile Access to NHC Pincer Complexes: Isolated Intermediates and Mechanism.

3. Experimental and Theoretical Study of Ni^II - and Pd^II -Promoted Double Geminal C(sp³ )-H Bond Activation Providing Facile Access to NHC Pincer Complexes: Isolated Intermediates and Mechanism.