Literature DB >> 12613598

Direct Zn-diamine promoted reduction of C=O and C=N bonds by polymethylhydrosiloxane in methanol.

Virginie Bette1, André Mortreux, Christian W Lehmann, Jean-François Carpentier.   

Abstract

Ketones and imines are chemoselectively reduced at room temperature in methanol to the corresponding alcohols and amines in high yields in a one-step procedure using polymethylhydrosiloxane (PMHS) and a simple zinc-diamine catalyst.

Entities:  

Year:  2003        PMID： 12613598

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Asymmetric hydrosilylation of ketones catalyzed by complexes formed from trans-diaminocyclohexane-based diamines and diethylzinc.

Authors:  Jadwiga Gajewy; Jacek Gawronski; Marcin Kwit
Journal:  Monatsh Chem       Date:  2012-04-18       Impact factor: 1.451

2.  Manganese-Catalyzed Asymmetric Hydrosilylation of Aryl Ketones.

Authors:  Xiaochen Ma; Ziqing Zuo; Guixia Liu; Zheng Huang
Journal:  ACS Omega       Date:  2017-08-18

3.  New anionic rhodium complexes as catalysts for the reduction of acetophenone and its derivatives.

Authors:  Olga Bartlewicz; Magdalena Jankowska-Wajda; Hieronim Maciejewski
Journal:  RSC Adv       Date:  2019-01-04       Impact factor: 4.036
  3 in total

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