Literature DB >> 12610999

Deactivation processes of homogeneous Pd catalysts using in situ time resolved spectroscopic techniques.

Moniek Tromp1, Jelle R A Sietsma, Jeroen A van Bokhoven, Gino P F van Strijdonck, Richard J van Haaren, Ad M J van der Eerden, Piet W N M van Leeuwen, Diek C Koningsberger.   

Abstract

UV-Vis, combined with ED-XAFS shows, for the first time, the evolution of inactive Pd dimers and trimers, that are a possible first stage in the deactivation process of important palladium catalysed reactions, leading to larger palladium clusters and eventually palladium black.

Entities:  

Year:  2003        PMID: 12610999     DOI: 10.1039/b206758g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Detection of Palladium(I) in Aerobic Oxidation Catalysis.

Authors:  Jonathan N Jaworski; Scott D McCann; Ilia A Guzei; Shannon S Stahl
Journal:  Angew Chem Int Ed Engl       Date:  2017-02-20       Impact factor: 15.336

2.  Operando Spectroscopic and Kinetic Characterization of Aerobic Allylic C-H Acetoxylation Catalyzed by Pd(OAc)2/4,5-Diazafluoren-9-one.

Authors:  Jonathan N Jaworski; Caitlin V Kozack; Stephen J Tereniak; Spring Melody M Knapp; Clark R Landis; Jeffrey T Miller; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2019-06-25       Impact factor: 15.419

  2 in total

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