Literature DB >> 12610974

eta 6-Arene complexes of Ni(II), efficient catalysts for 1,3-butadiene and styrene polymerization.

Juan Cámpora1, María del Mar Conejo, Manuel L Reyes, Kurt Mereiter, Elisa Passaglia.   

Abstract

A simple procedure for the preparation of cationic arene complexes of Ni(II) of composition [Ni(eta 6-ArX)(eta 3-C3H5)]+[BAr'4]- (X = OH, H) is reported. These compounds are shown to behave as highly active catalysts for the polymerization of 1,3-butadiene and styrene.

Entities:  

Year:  2003        PMID： 12610974     DOI： 10.1039/b209838e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  New strategy for synthesis of hydroxyl-terminated poly(3-hexylthiophene) and its block copolymer using an η3-π-allyl hydroxyl-functionalized Ni(i) initiator.

Authors:  Xin Min; Changchao Zhan; Ping Yan; Zhigang Ye
Journal:  RSC Adv       Date:  2020-11-01       Impact factor: 4.036

2.  A novel synthetic strategy for hydroxyl-terminated polybutadiene containing high cis-1,4 contents based on a Ni(ii)-coordinated anionic initiating system.

Authors:  Xin Min
Journal:  RSC Adv       Date:  2019-11-29       Impact factor: 4.036
  2 in total

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