Literature DB >> 12610947

A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(I).

Hidetaka Nakai1, Yongjun Tang, Peter Gantzel, Karsten Meyer.   

Abstract

The synthesis and characterisation of a thallium(I) triscarbene complex of the chelating, tripodal carbene ligand 1,3,5-[tris(3-tert-butylimidazol-2-ylideno)methyl]-2,4,6-trimethylbenzene is reported, in which the thallium ion is coordinated by three N-heterocyclic carbene donors in a distorted trigonal planar environment.

Entities:  

Year:  2003        PMID： 12610947     DOI： 10.1039/b209071f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Reactive p-block cations stabilized by weakly coordinating anions.

Authors:  Tobias A Engesser; Martin R Lichtenthaler; Mario Schleep; Ingo Krossing
Journal:  Chem Soc Rev       Date:  2015-11-27       Impact factor: 54.564

2.  2,4,6-Trimethyl-1,3,5-tris-(morpholino-meth-yl)benzene.

Authors:  Hong-Ji Ma; Chen Xu; Zhi-Qiang Wang; Le Zhou; Bao-Ming Ji
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-05-03

3.  Tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl metal complexes, [TismPriBenz]M: a new class of metallacarbatranes, isomerization to a tris(N-heterocyclic carbene) derivative, and evidence for an inverted ligand field.

Authors:  Serge Ruccolo; Michael Rauch; Gerard Parkin
Journal:  Chem Sci       Date:  2017-05-02       Impact factor: 9.825

4.  Thallium(I) Tropolonates: Synthesis, Structure, Spectral Characteristics, and Antimicrobial Activity Compared to Lead(II) and Bismuth(III) Analogues.

Authors:  Krzysztof Lyczko; Monika Lyczko; Marzena Banasiewicz; Karolina Wegrzynska; Anna Ziółko; Anna Baraniak; Jan Cz Dobrowolski
Journal:  Molecules       Date:  2021-12-29       Impact factor: 4.411
  4 in total

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