Odiel River, acid mine drainage and current characterisation by means of univariate analysis.

Water pollution caused by sulfide oxidation responds to two geochemical processes: a natural one of temporal patterns, and the 'acid mine drainage', an accelerated process derived from the extractive activity. The Odiel River is located in Southwestern Spain; it flows to the south and into the Atlantic Ocean after joining the Tinto River near its mouth, forming a common estuary. There are three kinds of metallic mining in the Odiel River Basin: manganese, gold and silver, and pyrite mining, the latter being the most important in this basin, which is the object of this study. The main objective of the present study is centred in the characterisation of the sources responsible for the 'acid mine drainage' processes in the Odiel River Basin, through the sampling and subsequent chemical and statistical analyses of water samples collected in three types of sources: mine dumps, active mines and abandoned mines. The main conclusion is that mean pH values in the target area are remarkably lower than those in other active and abandoned mines outside of the study zone. On the contrary, mean values for heavy metal sulfates are much higher. Regarding mine dumps, mean values for pH, sulfates and heavy metals are within a similar range to those data known for areas outside the study zone. Copyright 2003 Elsevier Science Ltd.