Literature DB >> 12605483

Aldol- and Mannich-type reactions via in situ olefin migration in ionic liquid.

Xiao-Fan Yang1, Mingwen Wang, Rajender S Varma, Chao-Jun Li.   

Abstract

An aldol-type and a Mannich-type reaction via the cross-coupling of aldehydes and imines with allylic alcohols catalyzed by RuCl(2)(PPh(3))(3) was developed with ionic liquid as the solvent. The solvent/catalyst system could be reused for at least five times with no loss of reactivity.

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Year:  2003        PMID: 12605483     DOI: 10.1021/ol0273102

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Iridium-catalyzed 1,3-hydrogen shift/chlorination of allylic alcohols.

Authors:  Nanna Ahlsten; Antonio Bermejo Gómez; Belén Martín-Matute
Journal:  Angew Chem Int Ed Engl       Date:  2013-04-24       Impact factor: 15.336

  1 in total

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